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Thermal expansion coefficients (CTE).

Linear coefficient of thermal expansion for the engineering materials we run, sorted from lowest CTE (Invar) to highest (engineering plastics). Use it for thermal-stack calculations, optical mount stability, cryogenic dimensional shift, and dissimilar-metal-fit analysis.

Materials
32
Lowest CTE
Invar 36
1.3 ppm/°C
Highest metal
Magnesium
26 ppm/°C
Reference temp
20–100 °C

By value, ascending

Sorted from lowest expansion to highest.

CTE values in parts per million per degree (ppm/°C and ppm/°F). For typical 20–100 °C reference range. Note: CTE varies modestly with temperature — for cryogenic or high-temperature applications, look up the CTE at your operating range, not just at room temperature.

Material Family CTE (ppm/°C) CTE (ppm/°F)
Invar 36(20–100 °C) Low-CTE alloy 1.3 0.7
Tungsten (W) Refractory metal 4.5 2.5
Tantalum (Ta) Refractory metal 6.5 3.6
Niobium (Nb) Refractory metal 7.3 4.1
Titanium Ti-6Al-4V Titanium alloy 8.6 4.8
Titanium CP Grade 2 Pure titanium 8.6 4.8
Stainless 410 Martensitic stainless 9.9 5.5
Tool steel H13 Tool steel 10.4 5.8
Tool steel D2 Tool steel 10.6 5.9
Tool steel A2 Tool steel 10.6 5.9
Stainless 17-4PH PH stainless 10.8 6
Hastelloy C-276 Nickel superalloy 11.2 6.2
Steel 1018 (mild) Carbon steel 11.7 6.5
Steel 4140 Alloy steel 12.2 6.8
Steel 4340 Alloy steel 12.2 6.8
Inconel 625 Nickel superalloy 12.8 7.1
Inconel 718 Nickel superalloy 13 7.2
Monel 400 Nickel alloy 13.9 7.7
Stainless 316L Austenitic stainless 16 8.9
Copper C110 (ETP) Pure copper 16.9 9.4
Stainless 304 Austenitic stainless 17.3 9.6
Beryllium copper C172 Cu-Be alloy 17.8 9.9
Bronze C932 Bearing bronze 18 10
Brass C360 Free-machining brass 20.5 11.4
MIC-6 cast aluminum Cast aluminum plate 23 12.8
Aluminum 2024-T3 Aerospace aluminum 23.2 12.9
Aluminum 6061-T6 Aluminum 23.6 13.1
Aluminum 7075-T6 Aerospace aluminum 23.6 13.1
Magnesium AZ31 Magnesium 25.9 14.4
PEEK(below Tg) Engineering plastic 47 26.1
Ultem (PEI) Engineering plastic 56 31.1
Delrin / POM Engineering plastic 110 61.1

Why this matters

Thermal stack-up arithmetic.

  • A 12″ aluminum part swings 0.016″ over a 100°F change.

    12 in × 13.1 ppm/°F × 100°F = 0.0157″. Multiply that by the number of dissimilar-metal interfaces in your assembly and you can see why aerospace optical-bench designs lean hard on Invar.

  • Dissimilar metals: subtract the CTEs.

    A bushing pressed in an aluminum housing using a titanium pin — Δ CTE = 23.6 − 8.6 = 15 ppm/°C. Over a 60°C swing on a 25 mm bushing: 25 × 15 × 60 / 1,000,000 = 0.023 mm of differential. Either accept it, design clearance for it, or pick same-CTE materials.

  • Cryogenic CTE is not the room-temp value.

    Most metals contract more slowly per degree at very low temperatures. For 4 K and 77 K dimensional analysis (cryostat hardware, superconducting magnets), use cryogenic-specific contraction data — it’s not a linear extrapolation from 20 °C values.

  • Plastics expand 3–4× more than metals.

    Delrin (POM) at 110 ppm/°C will move >0.001″ per inch per 10 °C. For tight-tolerance plastic features, design with thermal expansion explicitly in the calculation — and consider PEEK (47 ppm/°C) for tighter applications.

  • Match the CTE for sensitive optical/sensor work.

    Mounting an Invar-grade structure to an aluminum baseplate creates massive thermal stresses. For optical benches, sensor mounts, and dimensional-stability hardware, match CTE within ~3 ppm or accept the consequences.

Technically reviewed by the True Precision Machining engineering team · Last reviewed June 2026

Standards referenced: MMPDS (MIL-HDBK-5), ASTM E228, ASTM E831

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